Enhancing the processes of thermochemical treatment of oil

Volume 4, Issue 1, February 2021     |     PP. 1-13      |     PDF (437 K)    |     Pub. Date: May 24, 2021
DOI: 10.54647/chemical53030    89 Downloads     26018 Views  

Author(s)

Ab.H. Rzayev, Institute of Control Systems, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
R.Sh. Asadova, Institute of Control Systems, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
Gurbanov Z.G., Baku Higher Oil School, Baku, Azerbaijan

Abstract
A systematic analysis of the state of the art in the methods for enhancing processes of thermochemical treatment of oil is carried out. A new method and a new system for controlling the process of dynamic settling of oil emulsion (OE) is developed, which allows increasing the efficiency of managing the process of dynamic settling by more accurately measuring the degree of phase separation, while avoiding the process of “flooding”. The mechanism of formation of an electrical double layer around emulsified water droplets (EWD) and the interaction energy of these droplets as a distance function is shown. An adequate mathematical model of hindered settling of EWD is proposed. It is shown that OE and IEL can be broken down by using microwave radiation.

Keywords
Oil emulsion,Settler,Water cushion, Intermediate emulsion layer, Dynamic settling

Cite this paper
Ab.H. Rzayev, R.Sh. Asadova, Gurbanov Z.G., Enhancing the processes of thermochemical treatment of oil , SCIREA Journal of Chemical Engineering. Volume 4, Issue 1, February 2021 | PP. 1-13. 10.54647/chemical53030

References

[ 1 ] S.G. Lutoshkin, Gathering and treatment of oil, gas and water for transport (in Russian), M.: Nedra, 1972, 324 p.
[ 2 ] G.N. Pozdnyshev, Stabilizing and breaking oil emulsions (in Russian), M.: Nedra, 1982, 221 p.
[ 3 ] I.L. Markhasin, Physical and chemical mechanics of oil reservoir (in Russian), Moscow, Nedra, 1977, 214 p.
[ 4 ] Ab.G. Rzayev, G.I. Kelbaliyev, G.I. Mustafayeva, S.R. Rasulov, Simulation of the formation and breakdown of emulsion during thermochemical treatment of oil (in Russian). Chemistry and Technology of Fuels and Oils, Moscow, 2018, No.3, pp. 11-18.
[ 5 ] Innovation. Microwave method of breaking oil emulsions (in Russian). Oil and Gas Technologies, Moscow, No1, 2001, pp.107-108.
[ 6 ] T.A. Aliyev, Ab.G. Rzayev, G.A. Guluyev, S.F. Babayev, I.A. Nuriyeva, Eurasian patent No 026554, 28.04.2017, Method and system for controlling the process of dynamic settling of oil emulsion,
[ 7 ] T.A. Aliyev, Ab.G. Rzayev, G.A. Guluyev, G.I. Kelbaliyev, I.A. Nuriyeva, Eurasian patent No 029244, 28.02.2018, Method and system for controlling the process of thermochemical dehydration of oil emulsion,
[ 8 ] Ab.G. Rzayev, The scientific foundations for calculating the design and management of processes of separation of oil emulsion in oil treatment and oil refining (in Russian). Dissertation for the degree of PhD in Engineering, Baku, Institute of Theoretical Problems of Chemical Technology, 1994
[ 9 ] Ab.G. Rzayev, S.R. Rasulov, I.A. Abbasova, S.N. Ragimova, Development of the system for controlling the process of dynamic settling of oil emulsion (in Russian). Equipment and Technologies for Oil and Gas Complex, Moscow, 2014, No 5, pp.40-43
[ 10 ] T.A. Aliev, G.A. Guluyev, Ab.G. Rzayev, Mathematical models of the intermediate emulsion layer in the settlers of the thermochemical oil treatment plant (in Russian). Oil Refining and Petrochemistry, Moscow, 2011, No.8, pp.50-53
[ 11 ] Emulsion science. Ed. Philip Sherman. Academic Press, London, 1968, 496 p.
[ 12 ] Ab.G. Rzayev, I.A. Nurieva, S.R. Rasulov, Investigation of the mechanisms of coalescence of dispersed phase droplets and separation of oil emulsions (in Russian). Equipment and Technologies for Oil and Gas Complex, Moscow, 2016, No 4, pp.64-67
[ 13 ] G.I. Kelbaliev, A.H. Rzaev, A.F. Guseinov, A.A. Kasumov, Sedimentation of the particles from a concentrated dispersed flox. Plenum publishing corporation. 0022-0841/91/6193-10645/ 1250C, 1992, c.365-368
[ 14 ] Adango Miandonye, Brittany Macdonald, Microware radiation induced Visbreaking of Heavy Crude Oil Journal of Petroleum Science Research (JPSR), Valume 3, Issu 3, 2014, pp .130-135.
[ 15 ] H. Abdurahman, Nour and Rosli, M. Yunus, A comparative study on emulsion demulsification by microware radiation and conventional heating. http/scialert.net/fulltext/?da=jas.2006,2307,2311
[ 16 ] Zarrin Nasri, Application of microware technology in asphaltene and viscosity reduction of iranian vacuum residue. Proseedings of Academicsera 3rd International Conference, Jacarta, Indonezia, 13-14 March, 2017, ISBN, 978-93-86083-39-0, pp. 46-49.
[ 17 ] Ab.G. Rzayev, S.N. Ragimova, S.R. Rasulov, I.A. Abasova, Developing a system for controlling and managing the processes of thermochemical treatment of oil (in Russian). Automation, Telemechanization and Communication in Oil Industry, Moscow, 2013, No 12, pp.38-41